An unusual case of symmetry-preserving isomerism.

نویسندگان

  • Daofeng Sun
  • Shengqian Ma
  • Jason M Simmons
  • Jian-Rong Li
  • Daqiang Yuan
  • Hong-Cai Zhou
چکیده

Two isomeric phases of the NbO-type structure have been discovered: PCN-16 (alpha phase) and PCN-16' (beta phase), and gas sorption studies revealed that the alpha phase possesses a larger surface area, leading to higher hydrogen and methane storage capacity as compared with the beta phase.

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عنوان ژورنال:
  • Chemical communications

دوره 46 8  شماره 

صفحات  -

تاریخ انتشار 2010